Selected Values of Heats of Combustion and Heats of Formation of Organic Compounds Containing the Elements 6, H, N, 0, B, And S

By Domelski, Eugene S.

Book Id: WPLBN0000662094
Format Type: PDF eBook:
File Size: 6.88 MB
Reproduction Date: 2005

Title:	Selected Values of Heats of Combustion and Heats of Formation of Organic Compounds Containing the Elements 6, H, N, 0, B, And S
Author:	Domelski, Eugene S.
Volume:
Language:	English
Subject:	Technology., Reference materials, Technology and literature
Collections:	Techonology eBook Collection
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Citation APA MLA Chicago S. Domelsk, B. E. (n.d.). Selected Values of Heats of Combustion and Heats of Formation of Organic Compounds Containing the Elements 6, H, N, 0, B, And S. Retrieved from http://self.gutenberg.org/

Description
Technical Reference Publication

Excerpt
Introduction: As part of a continuing program of collecting and evaluating data on the thermodynamic properties of organic compounds, selected values are reported here for the heats of combustion and heats of formation of 719 organic compounds containing the elements carbon, hydrogen, nitrogen, oxygen, phosphorus, and sulfur (CHNOPS). Certain classes of compounds, such as amino acids, carbohydrates, glyceryl esters, and peptides, have been covered exhaustively because of their prime relevance to biological processes. Other classes of compounds, such as hydrocarbons, alcohols, acids, ketones, esters, aldehydes, were treated in a more cursory and limited manner. These latter classes contain compounds of natural biological occurrence, and have been included because a large group of common organic substances, such as ethanol, acetic acid, acetone and the like, have structmes and interactions equivalent or similar to substances occurring in biological systems. The latter classes are also needed to provide?

Table of Contents
Contents Page 1. Introduction ........................................... 222 6.16. Aromatic acids and phenylated aliphatic 2. Arrangement of the Data ... ... ... ... .............. 222 acids.. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3. Generalized Combustion Reactions for 6.17. Acid anhydrides ... . . . . . . . . . . . . . . . . . . . . . . . . . . . . . CHNOPS Compounds ... ......................... 223 6.18.Methyl esters of monobasic aliphatic 4. Development of Combustion Calorimetry.. . . . . 223 acids.. . . . . . . . . . . . . . . . . . . . . . . . . , . , . . . . . .. . . . . . . . . . 5. Corrections to the Combustion Data ............. 224 6.19. Methyl esters of monobasic aromatic 5.1. Calibration correction.. . . . . . . . . . . . . . . . . . . . . . . 224 acids.. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5.2. Vacuumcorrection ........................... 224 6.2O.Dimethyl esters of dibasic aliphatic 5.3. Molecular weight correction .........,...... 224 acids.. . . . . . . . . . . . . . . . . . . . . . . . .. . . . . . . . . . . . . . . . 5.4. Washburn correction ......................... 224 6.21. Dimethyl esters of dibasic aromatic 5.5. ArrRT cul~ac~ioi.l. .. .. . . . . . . . . . . . . . . . . . . , . . . . . . 225 acids... . . . . . . .. . . . . . . . . . . . . . . . . . . . . . , . . . . . . . . . . . 5.6. Temperature correction ... ... . .. ...... .. .. .. 225 6.22. Glyceryl esters. .. ............................... 5.7. Calculation of the standard heat of 6.23. Steroids.. . . . . . . . . . . . .. . . . . . . . . . . . . . . . . . . . . . . . .. . . . formation ..................................... 225 6.24. Lactones.. . . . . . . . . . . .. . ... . . . . . . . . . . . . . . .. . . . .. . .. 5.8. Units and constants ... ... ... ................. 225 6.25. Monosaccharides ... . . . . . . . . . . .. . . . . .. . . . . . . . . . . 5.9. Uncertainty in the data ..................... 225 6,26. Dissaccharides.. . . .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5.10. Acknowledgements ... ... :.. .................. 225 6.27. Oligosaccharides ... .. . . . . . . . . . . . . . . . . . . . . .. . . . . 6. Classes of compounds and selected values. .. . . . 226 6.28. Heterocyclic oxygen compounds ... ........ 6.1. Aliphatic hydrocarbons.. . . . . . . . . . . . . . . . . . . . . . 226 6.29. Aliphatic amines . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 6.2. Alicyclichydrocarbons ....................... 226 6.30. Aromatic amines ... .. . . . . . . . . . . . . . . . . . . . . . . . . . . 6.3. Aromatic hydrocarbons ... ........... ... . ... .. 227 6.31. Aliphatic amides . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 6.4. Aliphatic alcohols ... ... ... ... ................. 229 6.32. Aromatic amides . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 6.5. Phenols ... . .. . .. .......... .. . ... ...... ... .. .... .. . 230 6.33. Urea, guanidine, and their derivatives.. ... 6.6. Aliphatic di- and polyols ... .................. 231 6.34. Aliphatic amino acids ... ...................... 6.7. Ethers ............................................. 231 6.35. Aromatic amino acids, and aliphatip 6.8. Aldehydes ... ..................................... 232 amino acids containing a phenyl 6.9. Ketones ... ... ............. ...... . ........ ... ... ... 232 group ............................................ 6.10. n-Aliphatic acids ... . .. . . . . . . . . . . . . . . . . . . . . . . . . . 233 6-36. Amino acid anhydrides (diketopipera- 6.11. Hydroxy and keto aliphatic acids ... ....... 235 zines). . . . . . . . . ., . . . . . . , . -. . . . . . . . . . . . . . . . . . . . . . . 6.12. Unsaturated aliphatic acids ... ... ... ... ..... 235 6.37. Peptides . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 6.13. Aliphatic dicarboxylic acids.. . . . . . . . . . . . . . . . 236 6.38. Alkaloids ... ... . .. .. . ....... ....... . . . ............ 6.14. Hydroxy and keto aliphatic dicarboxylic 6.39. Heterocyclic nitrogen compounds ... ... ... acids ............................................ 236 6.40. Porphyrins ... ... ... ........ .... .... .. ...... ...... 6.15. Unsaturated aliphatic dicarboxylic acids.. 237 6.41. Organic sulfur compounds ....... .. . ... ... .. . 'Supported in part by the National Aeronautics and Space Adminis 6.42..0rganic Sulfur compounds containing tration under a program for obtaining thermodynamic data on hie logically related mate~ialaim portant in the apace program. nitrogen andlor oxygen .... .. ... .......... . 6.43. Organic phosphorus compounds ... ... ..... 7. References ................... .. ............-.-....... Copyright @ 1972 by the U.S. Secretary of Commerce on behalf of the United States. This 8. Compound index.. .. . . .. . . ,. . . . . . . . . ., .. , copyright will be assigned to the American Institute of Physics and the American Chemical Sooiety, to whom mu rsquo.ts resarding raproduction should be nddrsr~ed. 9. Miscellaneous comments ... . .. . .. ..- ............... 221 J. Phys. Chem. Ref. Dutu,VoI. 1, NO. 2, 1972